Search results for "law of thermodynamics"
showing 10 items of 12 documents
QSAR Modeling ANTI-HIV-1 Activities by Optimization of Correlation Weights of Local Graph Invariants
2004
Results of using descriptors calculated with the correlation weights (CWs) of local graph invariants for modeling of anti-HIV-1 potencies of two groups of reverse transcriptase (RT) inhibitors are reported. Presence of different chemical elements in molecular structure of the inhibitors and the presence of Morgan extended connectivity values of zeroth-, first- and second order have been examined as local graph invariants in the labeled hydrogen-filled graphs. By Monte Carlo method optimization procedure, values of the CWs which produce as large values as possible of correlation coefficient between the numerical data on the anti-HIV-1 potencies and values of the descriptors on the training s…
Basic Notions of the Theory of Heat
2016
This chapter summarizes some basic notions of thermodynamics and defines the empirical variables which are needed for the description of thermodynamic systems in equilibrium. Empirical temperature and several scales used to measure temperature are defined. The so-called “zeroth law of thermodynamics” is formulated which says that systems which are in mutual equilibrium have the same temperature. Thermodynamic ensembles corresponding to different macroscopic boundary conditions are introduced and are illustrated by simple models such as the ideal gas. Also, entropy appears on the scene for a first time, both in its statistical and its thermodynamical interpretation. Gibb’s fundamental form i…
On the divide between animate and inanimate
2015
Vitalism was abandoned already for a long time ago, yet the impression that animate beings differ in some fundamental way from inanimate objects continues to thrive. Here, we argue that scale free patterns, found throughout nature, present convincing evidence that this demarcation is only imaginary. Therefore, all systems ought to be regarded alike, i.e., all are consuming free energy in least time. This way evolutionary processes can be understood as a series of changes from one state to another, so that flows of energy themselves naturally select those ways and means, such as species and societies or gadgets and galaxies to consume free energy in the least time in quest of attaining therm…
Quantum evolution of near-extremal Reissner-Nordstrom black holes
2000
We study the near-horizon AdS_2\timesS^2 geometry of evaporating near-extremal Reissner-Nordstrom black holes interacting with null matter. The non-local (boundary) terms t_{\pm}, coming from the effective theory corrected with the quantum Polyakov-Liouville action, are treated as dynamical variables. We describe analytically the evaporation process which turns out to be compatible with the third law of thermodynamics, i.e., an infinite amount of time is required for the black hole to decay to extremality. Finally we comment briefly on the implications of our results for the information loss problem.
On the renormalization of ultraviolet divergences in the inflationary angular power spectrum
2015
We revise the role of ultraviolet divergences of cosmological observables and the corresponding renormalization from a space-time perspective. We employ the two-point function of primordial perturbations generated during inflation to derive an analytic expression for the multipole coefficients Cl in the Sachs-Wolfe regime. We analyzethe ultraviolet behaviorand stress the fact that the standard result in the literature is equivalent to a renormalization of the two-point function at zeroth adiabatic order. We also argue that renormalization at second adiabatic order seems to be more appropriate from a physical point of view. This may change significantly the predictions for Cl, while maintain…
Thermodynamics based on the principle of least abbreviated action: Entropy production in a network of coupled oscillators
2006
We present some novel thermodynamic ideas based on the Maupertuis principle. By considering Hamiltonians written in terms of appropriate action-angle variables we show that thermal states can be characterized by the action variables and by their evolution in time when the system is nonintegrable. We propose dynamical definitions for the equilibrium temperature and entropy as well as an expression for the nonequilibrium entropy valid for isolated systems with many degrees of freedom. This entropy is shown to increase in the relaxation to equilibrium of macroscopic systems with short-range interactions, which constitutes a dynamical justification of the Second Law of Thermodynamics. Several e…
Systematic derivation of hydrodynamic equations for viscoelastic phase separation
2021
(abridged) We present a detailed derivation of a simple hydrodynamic two-fluid model, which aims at the description of the phase separation of non-entangled polymer solutions, where viscoelastic effects play a role. It is directly based upon the coarse-graining of a well-defined molecular model, such that all degrees of freedom have a clear and unambiguous molecular interpretation. The considerations are based upon a free-energy functional, and the dynamics is split into a conservative and a dissipative part, where the latter satisfies the Onsager relations and the Second Law of thermodynamics. The model is therefore fully consistent with both equilibrium and non-equilibrium thermodynamics.…
Charm quark mass with calibrated uncertainty
2016
We determine the charm quark mass ${\hat m}_c({\hat m}_c)$ from QCD sum rules of moments of the vector current correlator calculated in perturbative QCD. Only experimental data for the charm resonances below the continuum threshold are needed in our approach, while the continuum contribution is determined by requiring self-consistency between various sum rules, including the one for the zeroth moment. Existing data from the continuum region can then be used to bound the theoretical error. Our result is ${\hat m}_c({\hat m}_c) = 1272 \pm 8$ MeV for $\hat\alpha_s(M_Z) = 0.1182$. Special attention is given to the question how to quantify and justify the uncertainty.
Substitution systems and nonextensive statistics
2015
Abstract Substitution systems evolve in time by generating sequences of symbols from a finite alphabet: At a certain iteration step, the existing symbols are systematically replaced by blocks of N k symbols also within the alphabet (with N k , a natural number, being the length of the k th block of the substitution). The dynamics of these systems leads naturally to fractals and self-similarity. By using B -calculus (Garcia-Morales, 2012) universal maps for deterministic substitution systems both of constant and non-constant length, are formulated in 1D. It is then shown how these systems can be put in direct correspondence with Tsallis entropy. A ‘Second Law of Thermodynamics’ is also prove…
Answering Schrödinger's "What Is Life?"
2020
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